Formation of nanostructured polymer filaments in nanochannel reactors

IEC 37

Chih-Yi Peng1, Stephen J. Fonash1, Bin Gu2, Ayuaman Sen2, Seong H. Kim3, and Henry C. Foley3. (1) Nanofabrication facility, Penn State University, University Park, PA 16802, (2) Department of Chemistry, Pennsylvania State University, University Park, PA 16802, (3) Department of Chemical Engineering, The Pennsylvania State University, 118B Fenske Laboratory, University Park, PA 16802
Channels with nanodimensional cross-sections were fabricated by e-beam lithography and top-down silicon processing and used as templates for controlled polymerization. The dimensions of these nanotemplates are 20 nm high, 20 nm to 200 nm wide, and 100 mm long. It was established that these channels are open all the way without any collapsed regions. Nanostructured polymer filaments with controlled size, location and orientation were grown inside the channels by either radical or coordination polymerization. The presence of the polymers in the channels was verified by O2 plasma etching, fluorescence mapping, and solubility test. The polymer filaments produced are continuous and, when released from the template, can twist without breaking.